Thermal Gravimetric Analysis

Thermogravimetric analysis (TGA) is conducted on an instrument referred to as a thermogravimetric analyzer. A thermogravimetric analyzer continuously measures mass while the temperature of a sample is changed over time. Mass, temperature, and time in thermogravimetric analysis are considered base measurements while many additional measures may be derived from these three base measurements.

A typical thermogravimetric analyzer consists of a precision balance with a sample pan located inside a furnace with a programmable control temperature. The temperature is generally increased at constant rate (or for some applications the temperature is controlled for a constant mass loss) to incur a thermal reaction. The thermal reaction may occur under a variety of atmospheres including: ambient air, vacuum, inert gas, oxidizing/reducing gases, corrosive gases, carburizing gases, vapors of liquids or “self-generated atmosphere”; as well as a variety of pressures including: a high vacuum, high pressure, constant pressure, or a controlled pressure.

The thermogravimetric data collected from a thermal reaction is compiled into a plot of mass or percentage of initial mass on the y axis versus either temperature or time on the x-axis. This plot, which is often smoothed, is referred to as a TGA curve. The first derivative of the TGA curve (the DTG curve) may plotted to determine inflection points useful for in-depth interpretations as well as differential thermal analysis.

A TGA can be used for materials characterization through analysis of characteristic decomposition patterns. It is an especially useful technique for the study of polymeric materials, including thermoplastics, thermosets, elastomers, composites, plastic films, fibers, coatings, paints, and fuels.

TGA can be used to evaluate the thermal stability of a material. In a desired temperature range, if a species is thermally stable, there will be no observed mass change. Negligible mass loss corresponds to little or no slope in the TGA trace. TGA also gives the upper use temperature of a material. Beyond this temperature the material will begin to degrade.

TGA is used in the analysis of ceramics and thermally stable polymers. Ceramics usually melt before they decompose as they are thermally stable over a large temperature range, thus TGA is mainly used to investigate the thermal stability of polymers. Most polymers melt or degrade before 200°C.

The TGA instrument continuously weighs a sample as it is heated to temperatures of up to 2000 °C for coupling with FTIR and Mass spectrometry gas analysis. As the temperature increases, various components of the sample are decomposed and the weight percentage of each resulting mass change can be measured.